determination of melting point and boiling point experiment

Talk to our experts

1800-120-456-456

CBSE Chemistry Experiment Determination of Melting Point

Chemistry Experiment - Determination of Melting Point

The melting process is the most common and well-known physical change observed by one. The melting of a solid is an example of melting ice into water, melting butter in a pan, etc. These all show a state change from solid to liquid, and this change is known as melting. 

The process of melting helps in the determination of a substance's melting point. Determination of the melting point of an organic compound is greatly useful to check the compound's properties, such as its bulky nature, nature of bonding, and force of attraction between molecules.    

Table of contents

Apparatus Required

The procedure of melting point determination of the given sample/compounds.

Table to identify the given sample/compound with known melting points

Determination of Boiling point of Organic Compounds

Observation

Precautions

To determine the melting point of the given solid compounds and identify the nature of the compounds. 

Materials Required

Thermometer

Tripod Stand

Kerosene burner

Capillary tube (9 to 10 cm long and 0.5 to 2 mm diameter)

Paraffin oils

The melting point theory is greatly influenced by the nature of bonding and the force of attraction between molecules.

The following types of bonding present in the molecules are intermolecular forces, Van der Waal forces, dipole-dipole interactions, ion-ion interactions, and hydrogen bonding.  

The bonding strength is as follows- Ion-ion interactions > Hydrogen bonding > Dipole-dipole interactions > London dispersion forces > Van der Waal forces.

Therefore, the force of attraction between molecules majorly affects the melting point of a compound. The stronger the force of attraction between molecules, the more the melting point of a compound/sample.  

Carbon-bonded or non-polar compounds have weak Van der Waal forces of attraction and dipole-dipole interactions. Hence, the melting point for such compounds is generally low compared to polar compounds. Examples include phenol, oxalic acid, naphthalene, urea, etc. 

The polar compounds have ion-ion interactions because of the electrostatic force of attraction and have very high melting points. Examples include sodium chloride, magnesium oxide, etc. 

If the given samples show a drastic melting point difference between them, it shows the nature of bonding in the molecules. 

A sharp melting point indicates the purity of the organic compound. It melts over a narrow range of temperature differences of about 0.5 °C to 1 °C. The organic compound contains impurities if the temperature difference exceeds this range.  

Take the given samples (1 and 2) and crush them into fine powder.

Take the capillary tube and prepare it by closing one end by heating it. 

Put the capillary tube into the compounds at the open end.  

The filling of the compounds is about 1-2 cm in the capillary tube by gently tapping it.  

Attach the capillary tube with the thermometer with the help of a thread and attach it with a clamp. 

Place the wire gauge on the tripod stand and keep a beaker containing paraffin oil.

Provide continuous heat to the beaker with a burner and dip the thermometer into it.

The melting point apparatus diagram is as follows-

The iron stand and clamp are set up initially, and the thermometer is attached to the clamp and inserted into the beaker. 

The sample in the capillary tube is attached to the thermometer, which is inserted into the beaker.

The beaker filled with liquid paraffin is placed over the wire gauge, which is settled up by the tripod stand. 

The continuous heat is supplied to the beaker to maintain the constant temperature by the Bunsen burner.

Melting Point Apparatus

Note the temperature when the given compounds/samples start melting and completely melt in the following manner-

The temperature when the compound starts melting, say the initial temperature (t 1 °C).

The temperature when the compound completely melts, says the final temperature (t 2 °C). 

 The correct melting point of the compound is determined by an average of two temperatures, t 1, and t 2 , and the formula is - \[\left( {\dfrac{{t_1^^\circ C + t_2^^\circ C}}{2}} \right)\] .

Observation 

Melting Point of Sample 1

Melting Point of Sample 2

Identification of given samples (observed melting points) with known melting points of organic compounds 

From the above data, the melting point of sample 1 is 79.60 °C, which is similar to naphthalene. 

The melting point of sample 2 is 122.2 °C, which is similar to benzoic acid. 

From the above analysis, sample 1 is naphthalene and sample 2 is benzoic acid. 

The different melting points of the two samples are due to differences in their structure and nature of bonding.

The compound Naphthalene (C 10 H 8 ) has a fused or condensed ring of hydrocarbon compound composed of two benzene rings sharing two adjacent carbon atoms. It has two rings with hydrogen bonding that make it a weak compound due to Van der Waals forces and non-polarity.

Whereas, the compound, benzoic acid (C 6 H 5 COOH), is composed of only one benzene ring with a carboxyl group. But it has intermolecular forces consisting of hydrogen bonding, dipole-dipole forces, and London dispersion forces.  

Therefore, benzoic acid has a higher melting point when compared to naphthalene.

The above experiment for the determination of the melting point of a compound gives the nature of bonding exhibits in the molecules. Hence, the melting point can be explained by one.

Always use powdered and dry samples (organic compounds).

The packaging of the organic compound should be uniform in the capillary tube, with no air gaps between the solid particles.

It is a necessary thermometer and capillary tube at the same level. 

Do not overfill the capillary tube, and gently tap the capillary tube after filling it with the sample.

Always supply uniform heating to the sample. 

Lab Manual Questions

1. What is melting point?

Ans. The melting point is usually defined as the point at which materials changes from a solid to a liquid. The temperature at which solid changes its state to liquid at atmospheric pressure is called the melting point of that liquid. This is the point at which both liquid and solid phase exists at equilibrium.

2. What liquid determines the melting point and why?

Ans. The liquid paraffin oil determines the melting point because it has a high boiling point and can maintain a high temperature without losing the substance.  

3. What is the melting point range of the organic compound?

Ans. The range where the melting point of the organic compounds can be varied and accepted is about 1 °C to 2 °C. 

4. Why should the melting point sample be finely powdered?

Ans. The organic sample should be finely powdered because it gives maximum surface area in contact with heat, and the heat is uniformly distributed and gives an exact melting point of the compound. 

Viva Questions

1. Is the melting point qualitative or quantitative?

Ans. The melting point is the physical properties that are easy to measure. Therefore, it is a quantitative property. 

2. What are the factors that influence the melting point?

Ans. The following factors affect the melting point are

Size of the molecule.

The shape of molecules.

Intermolecular forces.

Ionic bonds. 

3. Do impurities lower the melting point?

Ans. The presence of impurities disrupts the crystalline lattice of the organic compound and weakens the intermolecular force of attraction. Hence, it lowers the melting point.   

4. Which organic compound or group has the highest melting point?

Ans. The amide group has the highest melting point due to the formation of intermolecular hydrogen bonding. 

5. Can two compounds have the same melting point?

Ans. In the presence of millions of organic compounds, most of the compounds have melting points below 250 °C. Therefore, two different chemical compounds can have identical melting points. 

6. Why is it necessary to slowly heat your sample when taking a melting point?

Ans. It is necessary to heat the beaker containing liquid slowly to maintain the thermal equilibrium between the liquid and the thermometer. A slow change in the physical state of the compound and temperature on the thermometer is observed.    

7. What does it mean if the melting point was lower than the literature value?

Ans. If the melting point is lower than the literature value, it is due to the presence of impurities. 

8. Why is the melting point a physical property?

Ans. Physical property is a change in the physical state of the compound. When an organic compound is heated, its solid state changes into liquid, but the composition remains the same. Therefore, the melting point is a physical property. 

9. Does the molar mass of an organic compound affect the melting point?

Ans. Yes, the greater the molar mass, the higher the melting point.

10. What factors increase the melting point?

Ans. All organic compounds have different compositions, the nature of bonding, and the force of attraction between molecules. Polarity, especially hydrogen bonding, leads to a high melting point. Therefore, the polar organic compound has higher melting points than non-polar compounds of similar sizes.  

Practical Questions

1. What is the name of the process that occurs when a solid changes to a liquid?

Heating 

Ans. Melting is the process that changes the solid state into liquid. 

2. The melting point of the ice is

O degrees Fahrenheit

0 degrees Celsius

100 degrees Celsius

100 degrees Fahrenheit

Ans. 0 degree Celsius

3. You melt a compound, and it disappears: what should you do?

Compound changes to a liquid.

Compound sublimes.

Impurity is present in the compound.

A pure compound is present.

Ans. Compound sublimes.

4. What would affect the observed melting point if the sample was packed too much?

The melting point will be very high.

The melting point will be shallow.

The exact and sharp melting point is observed.

The sample will melt quickly, and a low melting point will be observed. 

Ans. The sample will melt quickly, and a low melting point will be observed. 

5. What would affect the observed melting point if the sample was heated too quickly?

The results are better.

The sample is pure and does not have impurities.

The reading at which the sample starts to melt, and the reading at which the sample is wholly melted, will not be able to be read properly.

There is no sample left in the capillary tube.  

Ans. The reading at which the sample starts to melt, and the reading at which the sample is wholly melted, will not be able to be read properly.

6. What would affect the observed melting point if the sample was not completely dry?

The compound would likely give the temperature at which its water evaporates.  

The melting point will be lowered because water is impure.

The melting point observed is higher.

The melting point is sharp and exact of the compound. 

Ans. The melting point will be lowered because water is impure.

7. You think you have isolated Tylenol in the lab. Since you don't trust your laboratory techniques, you want to prove to yourself that you have Tylenol before you ingest it. Using only melting point techniques, explain how you can prove that you have Tylenol.

Prepared samples subjected to heat to observe the melting point. 

Mix the substance you just isolated (presumably Tylenol) with actual Tylenol in a 1:1 ratio, and find the melting point of that mixture. Then compare that to the melting point of the actual Tylenol to determine if your isolated substance is Tylenol.

The compound is to be mixed with water to observe the melting point.

The impurities are removed from the sample to prepare the compound.    

Ans. Mix the substance you just isolated (presumably Tylenol) with actual Tylenol in a 1:1 ratio, and find the melting point of that mixture. Then compare that to the melting point of the actual Tylenol to determine if your isolated substance is Tylenol.

8. Why is it not successful to mix two components by simply stirring and then sampling them for the melting point?

This results in a very high melting point.

This results in a shallow melting point.

The two components mixing and stirring do not give a homogenous mixture, as a small and mixed sample would not represent both components. 

The sample results are impure.  

Ans. The two components mixing and stirring do not give a homogenous mixture, as a small and mixed sample would not represent both components. 

9. Which organic compound has the maximum melting point among the following?

Bromobenzene

o-dibromobenzene

p-dibromobenzene

M-dibromobenzene

Ans. p-dibromobenzene has the highest melting point because of the symmetry of the molecule. 

10. Which of the following elements has the highest melting point?

Ans. Chromium has the highest melting point and the tendency to form metallic bonding due to the presence of unpaired electrons in its d-shell.

From the above experiment, we concluded that the solid melting point depends on the force of attraction between molecules. The presence of hydrogen bonding and stronger intermolecular compounds have a higher melting point. Organic compounds with lower melting points have weak Van der Waal forces of attraction. Therefore, melting point is one of the physical properties of an organic compound. The melting point of compounds depicts the nature of bonding between atoms.  

FAQs on CBSE Chemistry Experiment Determination of Melting Point

1. Why is it necessary to pack the sample tightly at the melting point?

It is required to pack the sample tightly for the determination of melting point as it reaches the thermal equilibrium and produces a broader melting point. 

2. What increases the melting point of a polymer material?

Polymer materials have a high melting point due to the molecules' bulky side groups, double bonds, and ring structures. 

3. How do impurities affect melting points?

A pure crystalline organic compound gives a sharp and exact melting point. Even minor impurities will lower the compound's melting point and affect the crystalline lattice of the organic compound. It defects in the crystalline lattice, making it easier to overcome intermolecular interaction. Hence, lowers the melting point of the organic compound.

4. Why is there no change in temperature during the melting of a solid?

The reason is the latent heat of fusion. During the state change, all heat is required to overcome the force of attraction between the molecules. Therefore, no change in temperature occurs.

• High School
• You don't have any recent items yet.
• You don't have any courses yet.
• You don't have any books yet.
• You don't have any Studylists yet.
• Information

Melting point determination Lab Report

Organic chemistry lecture i (chem 2323), northwest vista college.

Students also viewed

• 1314+0114+Co Req+Packet
• 4.5 Maximum Volume Word Problems
• Gentics lab notes - allele genotype intro
• 3. Trends - Market movements can create a bewildering number of patterns and variations of
• Intro To the Human Body Lab
• Physio Ex Exercise 10 Activity 1 Hyperventilation

Related documents

• Alt key symbol part 2 - alt key
• Lecture+Notes+11+Integration+by+Subtitution
• Lecture+Notes+8+Antiderivatives
• Lecture+Notes+10+FTC+part+II+applications
• Exam 4 practice - Homework
• Lecture+Notes+12+Integration+by+Parts

Related Studylists

Preview text.

Determination of Melting Points

John Nguyen

Professor Saumil Christian

May 27th , 2021

Introduction Melting point is the temperature at which a solid melt and becomes a liquid is the melting point. At the particulate level, the equilibrium temperature corresponds to the unique vibrational energy level which is just sufficient to shake loose the surface layer of solid molecules from the attraction of the underlying solid layer, allowing them to enter the contacting liquid layer (Young, 2013). Melting point determination identify compounds or to check the purity of the compound. It is a standard practice to carry out a rapid melting point determination initially to establish an approximate melting point and the carry out at least two determination. By heating more gently temperature changing only about 2°C/min until two consistent values is obtained (Christian, 2021).

The mel-temp apparatus is setup which would use to find the melting points and be shown below in Figure 1 . Begin the calibration of the thermometer by finding the melting points of six pure organic compounds: adipic acid, benzil, cinnamic acid, p-dichlorobenzene, urea and salicylic acid. Observing each compound initial temperature which the oven will quickly ramp up. This part of the heating process should meet the melting point of the compound. The purpose of this lab was to compare the maximum of the collected melting point range data to the values from the literature to plot the calibration error.

Procedure The melting point determination experiment begin with six organic compounds: adipic acid, benzil, cinnamic acid, p-dichlorobenzene, urea and salicylic acid. Compare the six organic compounds literature values to the observed values to determine if the thermometer

Results The following data shows data table in Table 1 and calibration curve graph in Figure 1 of the melting points in literature against observed melting points of six organic compounds.

Table 1: Literature melting points opposed to Observed melting point.

Compounds Literature melting point (°C) Observed melting point (°C) Adipic acid 152 150 Benzil 97 98 Cinnamic acid 136 138 P-dichlorobenzene 53 55 Salicyclic acid 159 156 Urea 135 134

Figure 1: Calibration curve graph of the observed melting points comparing the literature melting points.

0406080100120140160180

180 f(x) = 0 x + 4² = 1

Observed melting points vs. Literature melting points

Literature melting points

Observed melting points

Discussion The six organic compounds were found to be pure compound. Because the observed temperature was almost equivalent as the literature temperature melting point range by a few degrees Celsius. This proved that the thermometer was calibrated corrected and the results of the second experiment was accurate. For the unknown compound with a melting point observed at 129 °C -130°C was determined the compound was either cinnamic acid or urea. It was discovered using a mixed melting point technique. By placing the unknown sample in the Mel-Temp apparatus and increase into a high temperature for it to go through the melting point at fast pace providing a rough idea where a temperature range would be. Once got a rough idea when the sample gone through a melting point. Run the experiment for the second time in a new tube and

O, J. C., & Young, J. (2013, January 1). True Melting Point Determination . ResearchGate. researchgate/publication/271513918_True_Melting_Point_Determination. Christian, S Melting point technique , 2021.

• Multiple Choice

Course : Organic Chemistry Lecture I (CHEM 2323)

University : northwest vista college.

• More from: o-chem by Bob Dole 14 14 documents Go to Studylist